Increasing crude oil prices and concerns with sustainability have led to a growing interest in producing chemicals and fuels from renewable sources. A major focus for the replacement of petroleum feedstock is biomass particularly lignocellulosic biomass; this type of biomass has the potential to provide sustainable sugar streams from a variety of high-volume materials including agricultural and forest residuals and also high-yielding bioenergy crops. One option for the conversion of lignocellulosic biomass into renewable fuel is the production of levulinic acid which is a versatile platform chemical. However current methods of levulinic acid synthesis often result in large amounts of side products and intractable materials or require expensive feedstock. Using these conventional methods the actual yield of levulinic acid from biomass rarely exceeds 66 percent and usually is much less. A method for maximizing the production of levulinic acid from biomass is needed. A UW–Madison researcher has developed an improved method of producing levulinic acid from biomass. The method comprises a two-stage acid-catalyzed treatment. First at least a portion of the pentoses present in the biomass feedstock are separated from the hexose sugars under mild acidic conditions to result in a biphasic sugar mixture consisting of a pentose-rich liquor and a hexose-rich solid. Then the pentose-reduced hexose-rich biomass fraction is treated to yield levulinic acid. Utilizing this two-stage process a maximum levulinic acid molar yield of about 66 percent based on the hexose content was obtained under optimized conditions. The method also may comprise separating the first aqueous acidic solution from hexose-rich solid so the pentoses in the solution can be converted into furfural or other compounds. Applications: 1) Conversion of biomass to levulinic acid 2) Production of a relatively pure pentose stream that can be converted into other compounds
1) Improves levulinic acid yield by reducing the amount of furfural in the reaction mixture which also reduces the amount of humins formed during levulinic acid production 2) Levulinic acid can be further upgraded to fuels and commodity chemicals.