Background: Oils produced by microalgae can be harvested and converted to biodiesel. New research has successfully improved the yield of oil from algae by using chemical triggers to regulate algal metabolic pathways. As a result CO2 is sequestered yield is increased and there is greater viability in producing clean energy to replace petroleum. Technology Description: Researchers at the University of California Davis have discovered a new method of chemical control that increases microalgae’s production of glycerol-based lipids.
Liquid biofuels for transport, including biodiesel, have to a certain extent been in use for a very long time. In recent years however, they are enjoying renewed interest in both developed and developing countries as a result of the need to curb rising emissions from the transport sector, reduce dependence on expensive fossil oil imports and increase farm incomes. An important advantage of biofuels is that they can easily be integrated into the existing transport infrastructure, thus avoiding the often prohibitive investment costs associated with other renewable options for the transport sector. Conventional, 1st generation biodiesel can be produced from various vegetable oils, such as rapeseed, palm, soybean and jatropha oil and animal fats. Biodiesel can have significant benefits in terms of GHG emissions and socio-economic development. However, some biodiesel production has also been criticized for causing deforestation, loss of local livelihood and for having a negative GHG emissions balance (when palm oil is produced on peat land)
Depending on the feedstock and conversion route, we can distinguish 1st and 2nd generation biodiesel (lately, even 3rd generation options are staring to emerge, e.g. from algae). 1st generation biodiesel, also known as lipid-derived diesel, can be produced from various vegetable oils, such as rapeseed, palm, soybean and jatropha oil and animal fats
Biodiesel is used as a diesel substitute, and is generally blended with fossil diesel to various degrees. In Europe, the fuel standard permits only up to 5% biodiesel blend, mainly due to limitations imposed by fuel and vehicle specifications. Using blends over 20% may require some modest vehicle adaptations. Higher biodiesel fuel blends are sometimes used in fleet vehicles (e.g. trucks and buses) (IEA Bioenergy, 2009).
Depending on the feedstock and conversion route, we can distinguish 1st and 2nd generation biodiesel (lately, even 3rd generation options are starting to emerge, e.g. from algae). 1st generation biodiesel, also known as lipid-derived diesel, can be produced from various vegetable oils, such as rapeseed, palm, soybean and jatropha oil and animal fats
There are various routes to produce 1st generation diesel-type fuels from biomass. Transesterification, the most common route, is a catalytic process where fat or oil is combined with an alcohol (usually methanol). Two important by-products of this conversion route are glycerin and animal feed in the form of press cakes. The alternative route, hydrogenation, a process resembling oil refining, has so far seen limited deployment, although it produces a renewable diesel of superior quality (with higher blending potential) to that obtained via transesterification (IEA Bioenergy, 2009).
Feasibility of technology and operational necessities
Production of biodiesel depends mainly on sufficient provision of economical vegetable oils and animal fats used as feedstock. The production of biomass, both food crops such as rapeseed and oil palm but also lignocellulose biomass for 2nd generation biofuels, is limited by the availability of land and crop yields.
In 2011, approximately 1.6 billion hectares of land area was used as permanent cropland (FAOSTAT, 2013). After excluding forest land, protected areas and land needed to meet increased demand for food crops and livestock, estimates of the amount of land potentially available for expanded crop production lie between 250 and 800 million hectares, most of which is found in tropical Latin America or in Africa (Fischer, 2008). The other source of increased feedstock supply is the increase of yields: intensification of land use through improved technologies and management practices. In most African countries yields are only a fraction of their potential and significant improvement can also be achieved in Asia and most parts of Latin America (even in Malaysia, where oil palm yields are already among the highest in the world) (FAO, 2008). However, yield improvements require significant investment into fertilizers, mechanization and training of farmers to improve agricultural practices.
IEA Bioenergy (2009) sums up the critical issues in biomass logistics as:
- “The specific properties of biomass: low energy density, often requiring drying and densification; seasonal availability and problematic storage requiring further pre-treatment.
- Factors limiting the supply: availability and appropriateness of mechanized equipment; and inadequate infrastructure to access conversion facilities and markets.”
The main solutions to these issues, according to the IEA Bioenergy (2009) are “the development of advanced densification and other pre-treatment technologies, diversifying procurement geographically and in terms of biomass types, and the optimisation of fuel supply chains from field to plant gate (including the development of specialized harvesting and handling equipment), leading to lowest delivered costs” (IEA Bioenergy, 2009).
Status of the technology and its future market potential
Status of the technology
Transesterification and hydrogenation are technically mature and commercially available 1st generation technologies that produce biodiesel from vegetable oil and animal fats. (IEA Bioenergy, 2009).
Market penetration in different regions / countries and future market potential
The bulk of global biodiesel production is in Europe, which accounts for the largest part of the global biodiesel supply (with Germany and France the largest European producers), as a result of past support for domestic biofuel production.
Other countries are planning to step up production of biodiesel, often seeking to take advantage of its export potential. In Brazil in 2008, the government mandated that all diesel fuel must contain 2% biodiesel, which will be raised to 5% by 2013. The Philippines also adopted a 2% biodiesel blend obligation. In Malaysia and Indonesia, the palm oil industries are looking to supply an increasing proportion of the country’s diesel (WWI, 2007). Palm oil, soy bean oil and other vegetable oils, oil seeds and biodiesel, are increasingly traded on a global scale in response to increasing demand for biodiesel in the EU and many other world regions. In 2004, an estimated 1 million tonnes (out of 23 million tonnes traded) of these commodities were used for energy purposes (Heinimö and Junginger 2009). There are indications that this volume has been increasing rapidly. Main producers and exporters of vegetable oils (and increasingly of biodiesel) are Malaysia and Indonesia for palm oil and Argentina for soy bean oil (IEA Bioenergy, 2009).
How the technology could contribute to socio-economic development and environmental protection
Bioenergy, of which bioethanol is only one form, can represent great promise or a great threat at the same time. If developed sustainably, it offers a number of benefits to the environmental, social and economic circumstances of a producing country, including:
Social development opportunities:
- Job creation in the agriculture and forestry sectors, which is particularly relevant for developing countries with significant unused land resources and a large pool of unskilled workers;
- Job creation in the industrial sector (e.g. a 125 million liter ethanol plant would employ cca 270 people (Gnansounou et al., 2005);
- Increasing farm incomes: provided the additional income is distributed equitably, increasing the income in the primary sector, which employs the majority of the workforce, can support rural development and significantly improve living standards;
- Increasing inclusion in the economic system: well-organized farmers unions can gain access to energy markets.
- Increasing energy security by producing and using biofuels locally, thus reducing the dependence on imported fossil oil;
- Saving foreign currency by displacing fossil oil imports;
- Earning foreign currency by producing biofuels for export.
- Diversifying the industrial sector.
- GHG savings: most biofuels offer net GHG savings compared to fossil fuels, unless land area containing high carbon stocks (eg. rainforest, peatland) is cleared to make way for biofuel feedstock plantations.
The above mentioned benefits will materialize only within a comprehensive adequate policy framework. In absence of a clear and consistently enforced set of policies promoting sustainable production of feedstock and the equitable distribution of proceeds from biofuel sales along the whole supply chain, increased development of biofuels can lead to the following problems:
- Direct and indirect land use change causing deforestation, loss of biodiversity and conflict with food production;
- Land grabbing and displacement of rural communities;
- Concentration of production and income by a small number of large farmers and agribusinesses;
- Loss of livelihood by poor rural communities;
- Increased GHG emissions from land clearing and unsustainable farming practices
Especially some biodiesel produced from palm oil has received criticism as in some regions it was associated with destruction of natural rain forests, and resulting loss of biodiversity and local livelihoods. In addition, whilst average data for the CO2 balance of palm oil based biodiesel indicates a net benefit (see Figure 3), the actual CO2 balance depends highly on the land use changes associated with the biodiesel production. A life cycle analysis of palm oil based biodiesel shows significant GHG emissions for palm oil planted on peat forest land (Ifeu, 2008) (see Figure 4)
href="http://en.wikipedia.org/wiki/File:BiodieselsCountryOfOrigin.jpg">http://en.wikipedia.org/wiki/File:BiodieselsCountryOfOrigin.jpg) based on data by the UK government (http://www.dft.gov.uk/pgr/roads/environment/rtfo/govrecrfa.pdf)
In 2004, the Roundtable on Sustainable Palm Oil (RSPO) was formed to develop and implement global standards for sustainable palm oil. Financial requirements and costs== Depending on the feedstock used and scale of the plant, production costs can differ significantly. Because of lower average costs, larger plants (of capacity greater than 200 million liters per year) have dominated among new installation, a trend similar to industrial production of bioethanol. Production costs range from roughly $0.50/l to $1.60/l, depending on whether waste feedstock or vegetable oil is used as the main input. In the case of the latter, production costs are dominated by feedstock cost (IEA Bioenergy, 2009). Figure 5 shows indicative production costs of conventional biodiesel based on exemplary project specifications. Figure 6 gives a range of costs for biodiesel and diesel production.
In general, the profitability of a biodiesel plant is highly dependent on the spread between the feedstock costs and the sales price for the biodiesel.
Clean Development Mechanism market status
[This information is kindly provided by the UNEP Risoe Centre Carbon Markets Group.]
Project developers of biodiesel projects under the CDM mainly apply the following CDM methdologies: AMS-III.T.: Plant oil production and use for transport applications and AMS-III.AK.: Biodiesel production and use for transport applications for small-scale projects and ACM17: Production of biodiesel for use as fuel for large-scale projects
As of March 2011, there are 8 biodiesel projects in the CDM pipeline, out of which 1 small-scale project is registered.
- E4tech (2008): Internal analysis, see [].
- International Energy Agency (2008): World Energy Outlook 2008. Paris.
- FAO (2008). The State of Food and Agriculture 2008 – Biofuels: prospects, risks and opportunities. Available at []
- FAOSTAT, (2013). Food and Agriculture Organisation of the United Nations (FAO) (2013). FAOSTAT.
- Fischer, G. (2008): Implications for land use change, Paper presented at the Expert Meeting on Global Perspectives on Fuel and Food Security, 18–20 February 2008. Rome, FAO.
- F.O. Licht (2009): ‘Biodiesel output in 2009 may grow slower’, F.O. Licht’s World Ethanol & Biofuels Report, 26 March 2009
- Heinimö, J. and Junginger, M. (2009): Production and trading of biomass for energy – an overview of the global status. Paper accepted by Biomass and Bioenergy
- IEA Bioenergy (2009): Bioenergy – a Sustainable and reliable Energy Source, available online on [][]
- Ifeu Institut (2008): LCA of palm oil biodiesel (PME): Life cycle comparison. Available at []
- World Watch Institute (2006): Biofuels for Transport, Global Potentials and Implications for Sustainable Energy and Agriculture, prepared by Worldwatch Institute for the German Ministry of Food, Agriculture and Consumer protection (BMELV) in coordination with the German Agency for Technical Cooperation (GTZ) and the German Agency of Renewable Resources (FNR), published by Earthscan, London
Low temperature method for production of multiple biofuels and products from oleaginous biomass feedstocksType:Product
Project ID: D2011-30 Background:Biomass of non-lignocellulosic origin is typically composed of one or more of three components – protein starch and oils (such as triacylglycerides or other lipids). One of the concerns with thermochemical processing of protein-containing biomass is contamination of bio-oil with nitrogen-containing compounds (such as pyrozole pyridine maltol etc.) derived from protein. N-containing fuels are of low quality and may not pass fuel standards due to formation of NOx upon combustion.
Background: Although the demand for biodiesel is rapidly growing internationally production of the fuel has been plagued by quality related problems. This in turn has caused a lack of consumer confidence in biodiesel compounded by continued competition with petroleum-based alternatives that are available at a better price point and higher quality. Although several measures of quality can be used a limiting factor is often the cold weather performance of biodiesel that is manifested as a \"cloud point\"" and \""pour point\"" temperature that is too high for the climate.
Electricity from waste: Novel Geobacter strains can utilize energy-dense sources in microbial fuel cellsType:Product
Microbial Fuel Cell (MFC) technology possesses many advantages over other fuel cell technologies especially in its low costs long lifetime sustainability and environmental safety. Geobacter sulfurreducens a non-pathogenic anaerobic bacteria is the leading candidate for use in MFC’s. It possesses significant growth conductivity and electricity generation characteristics that make for the most efficient MFC. Furthermore it has the ability to completely oxidize substrates to CO2 while utilizing an anode as the sole electron acceptor. In a recent breakthrough Dr.
Development of a More Stable and Methanol Tolerant Lipase for Improved Production of Biodiesel ProductsType:Product
Summary: Biodiesel is an attractive alternative to petrodiesel since it burns cleaner releases less CO2 is biodegradable and can be obtained from renewable sources. Additionally since biodiesel is compatible with current diesel engines there is a large potential market for biodiesel to enter. Current methods for biodiesel synthesis include base-catalyzed reactions and lipase-catalyzed reactions. Both of these reactions produce biodiesels in the form of fatty acid methyl esters (FAMEs) as well as glycerol which can also be purified and sold as a value-added product.
Recently developed reagents in synthetic organic chemistry are promising alternatives to those that have been used in industry for decades. In many cases the newer chemical methodologies and reagents are safer and more environmentally benign. The industrial production of biodiesel from triglycerides and fatty acids exemplifies a process that can be improved using state of the art reactions and reagents in organic chemistry.
The production of microalgae as a feedstock for refining into biodiesel requires optimization in the design of bioreactors. This technology provides that optimization by increasing the production of algae by maximizing the presence of the distributed solar energy during daylight and also providing the use of artificial lighting during the nonavailability periods of solar energy. Gas is injected in the algal slurry at the bottom of the bioreactor and travels to the top where it is separated from the liquid.
Background: New renewable sources of transportation fuel are needed to meet continuing demand. While the main focus has been on biomass-derived gasoline alternatives such as ethanol and other short-chain alcohols distillates with higher energy density such as diesel and jet fuel are required for the heavy transportation sector. Biodiesel is a biodegradable clean-burning combustible fuel made of medium- to long-chain hydrocarbons that can be used in most internal combustion diesel engines.
Background: Increasing energy costs and environmental concerns have emphasized the need to produce sustainable renewable fuels and chemicals. Fatty acids energy-rich primary metabolites are composed of long alkyl chains and used by cells for chemical and energy storage functions. They represent nature’s “petroleum” and can be isolated from plant and animal oils for the production of fuels and oleochemicals. biodiesel a major biologically produced long chain product is almost exclusively derived from plant oils today.
Background: Production of alternative fuels such as biodiesel is on the rise around the world and in the U.S due to a strong and growing desire to reduce dependency on petroleum derived diesel fuel and its unstable pricing. The acceptance of biodiesel has been slowed due to its higher cost relative to petroleum-derived diesel. The higher cost of biodiesel is directly related to the cost of feedstock used for biodiesel production which is often derived from crops also used for food.