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This document describes the Technology Roadmap and Program Plan that has guided the Carbon Sequestration Program in the United States since 2007. The report summarizes the program and the key accomplishments in its history, as well as the challenges confronting deployment and successful commercialization of carbon sequestration technologies. It includes the research pathways that will be used to achieve program goals and information on key contacts and Web links related to the program. This document is intended to be a valuable tool in engaging interested stakeholders.